Stop thinking of a matrix as a grid of numbers; think of it as a function that moves vectors: x↦Ax. The columns of A tell you everything: they are the images of the basis vectors. If Ae1=col1 and Ae2=col2, linearity determines where every other vector goes.
To rotate the plane 90° counterclockwise: e1=(1,0)↦(0,1) and e2=(0,1)↦(−1,0), so
R=(01−10)